Posible solution
If you want this option displayed for 'default config' also, just edit the app\code\core\Mage\Core\etc\system.xml file.
Look for something like this
<template_hints translate="label"> <label<Template Path Hints</label> <frontend_type>select</frontend_type> <source_model>adminhtml/system_config_source_yesno</source_model> <sort_order>20</sort_order> <show_in_default>0</show_in_default> <show_in_website>1</show_in_website> <show_in_store>1</show_in_store> </template_hints>replace
<show_in_default>0</show_in_default>with
<show_in_default>1</show_in_default>and clear the cache
Do the same for this section
<template_hints_blocks translate="label"> <label>Add Block Names to Hints</label> <frontend_type>select</frontend_type> <source_model>adminhtml/system_config_source_yesno</source_model> <sort_order>21</sort_order> <show_in_default>0</show_in_default> <show_in_website>1</show_in_website> <show_in_store>1</show_in_store> </template_hints_blocks>Be careful. When you enable these 2 from 'default config' you will also see template hints and block hints in the admin section.